School of Physical and Geographical Sciences  
 
 
CHE-20020 Organometallic Chemistry and the f-Block  
Co-ordinator: Dr Richard Jones    Room: LJ1.02, Tel:33039  
Teaching Team: Mrs Monica  Heaney, Dr Katherine  Haxton, Miss Nicola  Jervis, Dr Michael  Edwards, Dr Matthew  O'Brien, Dr Matthew  O'Brien,  Joseph  Harrity,  Nigel  Young  
Lecture Time: See Timetable...  
Level: 2 Credits: 15 Study Hours: 150  
School Office:
 
 
 
Programme/Approved Electives for

None

Available as a Free Standing Elective

No

Barred Combinations

None

Prerequisites

Satisfactory performance in Level I modules in Chemistry or Medicinal Chemistry

Description

This module aims to develop the principles of main group and transition metal organometallic chemistry and lanthanide/actinide chemistry, supported by preparative and analytical laboratory experience. The module will build upon material in level I modules and provide valuable material for future work at level III. Students will explore computational and group theoretical aspects of organometallic chemistry. Additionally a portion of the laboratory work involves a 1:1 face to face assessment which replicates situations which graduates typically encounter in their career where they are required to explain and defend their work and any conclusions they have drawn from their experiments.

Aims

1 To enlarge upon and make connections between the underlying ideas in inorganic chemistry utilising both theoretical and practical knowledge covered in earlier modules to give a rounded description of the properties of the elements
2 To develop complex data processing and analysis skills.
3 To develop experimental and analytical laboratory skills
4 To develop problem solving and scientific writing skills
5 To develop oral communication skills



Intended Learning Outcomes

Interpret nomenclature and describe methods for the synthesis of main group and transition metal organometallic compounds. will be achieved by assessments: 1,4
Rationalise the chemical reactivity and spectroscopic properties of organometallic compounds in terms of molecular structure and bonding. will be achieved by assessments: 1,4
Describe the important applications of organometallic compounds in materials chemistry and catalysis. will be achieved by assessments: 1.4
Deduce and analyse reaction pathways and mechanisms of reactions involving organometallic compounds. will be achieved by assessments: 1,4
Describe and explain the bonding in electron deficient compounds and the application of Wade's Rules. will be achieved by assessments: 1,4
Account for the reactivity and properties of the f-block elements and their compounds in terms of modern concepts in chemistry. will be achieved by assessments: 1,4
Apply preparative and analytical laboratory techniques to the synthesis of a variety of typical organometallic compounds. will be achieved by assessments: 2,5
Use the GAUSSIAN package to examine structural and spectroscopic properties of organometallic compounds will be achieved by assessments: 3
Maintenance of a laboratory diary will be achieved by assessments: 2,5

Study hours

20 hours lecture
24 hours laboratory classes
2 hours class tests
12 hours problem classes
92 hours personal study



Description of Module Assessment

01: Class Test weighted 20%
Two 1-hour class tests
Students answer questions (2 per class test) selected from a bank of seen questions posted on the KLE.

02: Laboratory Report weighted 10% (min pass mark of 40)
laboratory report on a selected practical
1000 word laboratory report. Students will prepare and submit electronically a full (maximum 1000 words) report on a selected practical which will be marked in a face-to-face session with one of the course tutors.

03: Computer Task weighted 5%
Assessment of computer based experiment
Students will complete a proforma containing the results of a computational exercise in organometallic chemistry

04: 2 Hour Unseen Exam weighted 50% (min pass mark of 35)
UNSEEN EXAM - 2 HOURS
The paper is split into two sections with a degree of choice in each section: Part A short answer questions, Part B long answer questions.

05: Laboratory Assessment weighted 15% (min pass mark of 40)
Laboratory proformas
Students will complete and submit two proformas containing the results of two selected practical experiments. The laboratory diary will also be assessed.


Version: (1.06B) Updated: 03/Mar/2013

This document is the definitive current source of information about this module and supersedes any other information.